Volume 9, Issue 10 (12-2013)                   HSR 2013, 9(10): 1094-1107 | Back to browse issues page

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Mohsen Sadani, Ehsan Abouee Mehrizi, Seyd Kamal Ghadiri. Investigating the isotherm and kinetics of lead and cadmium absorption from leachate of waste materials by natural sorbents. HSR 2013; 9 (10) :1094-1107
URL: http://hsr.mui.ac.ir/article-1-508-en.html
1- دانشجوي دکتري، مرکز تحقيقات محيط زيست، دانشگاه علوم پزشکي اصفهان، مربي، دانشکده بهداشت، دانشگاه علوم پزشکي و خدمات بهداشتي درماني شهيد صدوقي يزد، ايران
2- Department of Environmental Health Engineering, Faculty of Public Health, North Khorasan University of Medical Sciences, Bojnurd, Iran (Corresponding Author) Email: ehsan.abouee@gmail.com
3- PhD Student, Tehran university of Medical Sciences, Tehran, Iran
Abstract:   (891 Views)
Background: Presence of heavy metals in leachate due to the biological accumulation characteristics of these materials endangered the living creatures' health especially human. Purpose of this study is to study and investigate the possibility of two metals' absorption i.e, lead and cadmium from leachate by natural zeolite clinopteliolit and increase of the ability to absorb the zeolite by modified surface. Methods: To examine these two metals 'ability in absorption (lead and cadmium) and variables such as type of sorbent, sorbent concentration and contact time were studied. Zeolites samples used by the tests i.e, X-ray Florescence, the spectrum of X-ray diffraction and BET were analyzed for compound identification. Findings: The absorption efficiency of the modified zeolites was increased from 4.2 and 5.3 percent to 71.6 and 75.2٪ for lead and cadmium respectively. With increasing the surfactant concentration from 2 to 20 mmol/L, the absorption efficiency of modified zeolit for lead and cadmium was increased to 71 and 74%, respectively. The best isotherm model for lead adsorption was Freundlich model, with a determination coefficient equal to 0.99, and for cadmium it was Langmuir model with a determination coefficient equal to 0.99. Conclusion: The modified zeolite with surfactant can be used as an appropriate adsorbent for separation of heavy metals from waste leachate. Lead and cadmium absorbed in single layer on the modified zeolite with surfactant and with comparing parameters of different studied isotherm models indicated that the capacity of modified zeolite for lead adsorption was more than cadmium adsorption, but cadmium was absorbed with higher energy.
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Type of Study: Research | Subject: education health and promotion
Received: 2020/07/16 | Accepted: 2013/12/15 | Published: 2013/12/15

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